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https://repositorio.ufba.br/handle/ri/14634
metadata.dc.type: | Artigo de Periódico |
Title: | Aplicações sintéticas do ácido mucobrômico e da 3,4-dibromofuran-2(5H)-ona |
Other Titles: | Química Nova |
Authors: | Cunha, Silvio do Desterro Oliveira, Caio C. |
metadata.dc.creator: | Cunha, Silvio do Desterro Oliveira, Caio C. |
Abstract: | This review describes the use of two biomass-derivate butenolides as intermediates in organic synthesis, mucobromic acid and its reduced derivative 3,4-dibromofuran-2(5H)-one. The ambiphilic and ambident character of such butenolides make them versatile starting materials in the synthesis of natural and/or bioactive compounds. Thus, the reactions of mucobromic acid with C-nucleophiles and heteronucleophiles are described, as well as the nucleophilic addition to carbonyl reactions of 3,4-dibromofuran-2(5H)-one. Besides, both compounds are active in diverse metal cross-coupling reactions, manly with palladium in Suzuki and Sonogashira reactions. |
Keywords: | Mucobromic acid 3,4-dibromofuran-2(5H)-one Butenolides |
metadata.dc.rights: | Acesso Aberto |
URI: | http://repositorio.ufba.br/ri/handle/ri/14634 |
Issue Date: | 2011 |
Appears in Collections: | Artigo Publicado em Periódico (Química) |
Files in This Item:
File | Description | Size | Format | |
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Silvio Cunha.pdf | 1,34 MB | Adobe PDF | View/Open |
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