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https://repositorio.ufba.br/handle/ri/13611| metadata.dc.type: | Artigo de Periódico |
| Title: | Solvent Dependent Conformational Isomerism and Ligand Oxidation of Novel Ru(II) Cyclen Complexes |
| Other Titles: | Inorganic Chemistry |
| Authors: | Ferreira, Kleber Queiroz Cardoso, Luciana Nunes Nikolaou, Sofia Rocha, Zênis N. da Silva, Roberto S. da Tfouni, Elia |
| metadata.dc.creator: | Ferreira, Kleber Queiroz Cardoso, Luciana Nunes Nikolaou, Sofia Rocha, Zênis N. da Silva, Roberto S. da Tfouni, Elia |
| Abstract: | The synthesis of cis-[RuII(cyclen)(L)x]n+ (cyclen = 1,4,7,10-tetraazacyclododecane and L = 2,2‘-bipyridine (bpy), phenanthroline (phen) or 4-cyanopyridinium (4-NCpyH+)) is reported. The freshly prepared complexes are stable in aprotic solvents and cyclen undergoes oxidative dehydrogenation reaction at high pH. These compounds also present solvent dependent conformational isomerization. |
| metadata.dc.rights: | Acesso Aberto |
| URI: | http://repositorio.ufba.br/ri/handle/ri/13611 |
| Issue Date: | 2005 |
| Appears in Collections: | Artigo Publicado em Periódico (Química) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Kleber Q..pdf | 112,63 kB | Adobe PDF | View/Open |
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