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Please use this identifier to cite or link to this item: http://repositorio.ufba.br/ri/handle/ri/7756

Title: Flow injection determination of cobalt after its sorption onto polyurethane foam loaded with 2-(2-thiazolylazo)-p-cresol (TAC)
Other Titles: Talanta
Authors: Cassella, Ricardo Jorgensen
Salim, Veronica A.
Jesuı́no, Luciene S.
Santelli, Ricardo Erthal
Ferreira, Sergio Luis Costa
Carvalho, Marcelo Souza de
Keywords: Polyurethane foam;Cobalt;Solid phase extraction;Flow injection analysis
Issue Date: 2001
Abstract: This paper reports the development of a new methodology for determination of cobalt in water samples by using a flow injection system with loaded PUF as solid phase to preconcentrate analytes. Procedure is based on on-line retention of Co(III) ions (generated in alkaline medium by Co(II) oxidation) in a minicolumn packed with a polyether type polyurethane foam loaded with TAC (2-(2-thiazolylazo)-p-cresol) and elution with 2 mol l−1 HCl directly to the flame atomic absorption spectrometer nebulizer. Several chemical and flow variables that could affect the performance of this system were investigated as well as the possible interferents. For 2 min of preconcentration time (10.0 ml of sample volume) the system achieved a detection limit 3.2 μg l−1, a R.S.D. 5% at 20 μg l−1 and an analytical throughput 24 h−1. Whereas for 3 min of preconcentration time (15.0 ml of sample volume) a detection limit 2.4 μg l−1, a R.S.D. under 8% at 10 μg l−1 and a sampling frequency 17 h−1 were reported.
Description: Texto completo: acesso restrito. p. 61–67
URI: http://www.repositorio.ufba.br/ri/handle/ri/7756
ISSN: 0039-9140
Appears in Collections:Artigos Publicados em Periódicos (Quimica)

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