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DC Field | Value | Language |
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dc.creator | Pereira, Luis Gabriel Gomes | - |
dc.date.accessioned | 2023-11-21T15:55:27Z | - |
dc.date.available | 2023-11-21T15:55:27Z | - |
dc.date.issued | 2023-09-15 | - |
dc.identifier.uri | https://repositorio.ufba.br/handle/ri/38522 | - |
dc.description.abstract | Bio-oil from sisal residue, produced through the process of fast pyrolysis in a fluidized bed, has a differentiated composition, which stands out due to its high viscosity and pour point, low O/C ratio, high thermal stability and high content of phenols. However, it still needs to be improved in order to be used in biorefineries and for the production of chemical species of industrial interest. Therefore, the present work aims to evaluate the reduction of oxygenated species in the bio-oil from sisal residue by manipulating the operational variables of the fast pyrolysis process and its catalytic transformation via hydrodeoxygenation (HDO). The process/product relations of the pyrolysis were studied by varying the nitrogen flow rate, biomass mass flow rate, temperature and pressure. In general, the bio-oil composition was intensely dependent on the process parameters. The lowest pressure studied was the best condition for obtaining bio-oil with high yield (up to 17 wt%), with higher yield of monomers (44.51 wt%) and lower O/C ratio (0.11). The results also indicated that the bio-oil from the sisal residue has a composition with high levels of phenolic, aliphatic and naphthalene compounds. It has, therefore, great potential for obtaining biofuels and/or aromatics and phenols with high added value via catalytic upgrade, due to the low oxygen content and high degree of depolymerization. In the HDO step, Ni-Cu/Al-MCM-41 type catalysts were active in the hydrotreatment of bio-oils from sisal residue and pinewood. The bimetallic catalysts 20Ni5Cu and 20Ni10Cu showed the best performances, promoting yields of 53.1 wt% and 51.2 wt% in the organic phase, higher than the benchmark RU/C (47.1%), in addition to promoting yields of 43.35 wt% and 42.84 wt% of monomers, respectively. There was a reduction in the average molecular weight (Mw), as well as in the O/C ratio and an increase in the H/C ratio, indicating a predominance of the hydrogenation/hydrodeoxygenation/hydrocracking route. In the case of bio-oil from sisal residue, the repolymerization route was predominant, resulting in lower H2 uptake, increased Mw and reduced monomer yields. However, there was a reduction in the O/C ratio of approximately 48 wt% on average compared to the feed, as well as an increase in aliphatic and aromatic hydrocarbons, alcohols and ketones. | pt_BR |
dc.description.sponsorship | Capes | pt_BR |
dc.description.sponsorship | FAPESB | pt_BR |
dc.description.sponsorship | Banco do Nordeste | pt_BR |
dc.language | por | pt_BR |
dc.publisher | Universidade Federal da Bahia | pt_BR |
dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Brazil | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/br/ | * |
dc.subject | Bio-óleo | pt_BR |
dc.subject | Resíduo de sisal | pt_BR |
dc.subject | Pirólise rápida | pt_BR |
dc.subject | Hidrodesoxigenação catalítica | pt_BR |
dc.subject | Ni-Cu/Al-MCM-41 | pt_BR |
dc.subject.other | Bio-oil | pt_BR |
dc.subject.other | Sisal residue | pt_BR |
dc.subject.other | Fast pyrolysis | pt_BR |
dc.subject.other | Catalytic hydrotreatment | pt_BR |
dc.subject.other | Ni-Cu/Al-MCM-41 | pt_BR |
dc.title | Valorização do bio-óleo do resíduo de sisal | pt_BR |
dc.title.alternative | Valorization of bio-oil from sisal residue | pt_BR |
dc.type | Tese | pt_BR |
dc.contributor.referees | Campos, Leila Maria Aguilera | - |
dc.publisher.program | Programa de Pós-Graduação em Engenharia Quimica (PPEQ) | pt_BR |
dc.publisher.initials | UFBA | pt_BR |
dc.publisher.country | Brasil | pt_BR |
dc.subject.cnpq | CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA::PROCESSOS INDUSTRIAIS DE ENGENHARIA QUIMICA::PROCESSOS ORGANICOS | pt_BR |
dc.contributor.advisor1 | Pires, Carlos Augusto de Moraes | - |
dc.contributor.advisor1ID | https://orcid.org/0000-0003-4231-6495 | pt_BR |
dc.contributor.advisor1Lattes | http://lattes.cnpq.br/7185462874845405 | pt_BR |
dc.contributor.advisor-co1 | Lima, Sirlene Barbosa | - |
dc.contributor.advisor-co1Lattes | http://lattes.cnpq.br/4677727390063135 | pt_BR |
dc.contributor.referee1 | Pires, Carlos Augusto de Moraes | - |
dc.contributor.referee1ID | https://orcid.org/0000-0003-4231-6495 | pt_BR |
dc.contributor.referee1Lattes | http://lattes.cnpq.br/7185462874845405 | pt_BR |
dc.contributor.referee2 | Lima, Sirlene Barbosa | - |
dc.contributor.referee2Lattes | http://lattes.cnpq.br/4677727390063135 | pt_BR |
dc.contributor.referee3 | Trierweiler, Jorge Otávio | - |
dc.contributor.referee3ID | https://orcid.org/0000-0002-6328-945X | pt_BR |
dc.contributor.referee3Lattes | http://lattes.cnpq.br/5718970374865864 | pt_BR |
dc.contributor.referee4 | Silva Júnior, Roberto Batista da | - |
dc.contributor.referee4ID | https://orcid.org/0000-0002-6281-7820 | pt_BR |
dc.contributor.referee4Lattes | http://lattes.cnpq.br/8404741392766812 | pt_BR |
dc.contributor.referee5 | Varela, Maria do Carmo Rangel Santos | - |
dc.contributor.referee5ID | https://orcid.org/0000-0002-2497-9837 | pt_BR |
dc.contributor.referee5Lattes | http://lattes.cnpq.br/0023950321397451 | pt_BR |
dc.creator.ID | https://orcid.org/0000-0002-1055-0300 | pt_BR |
dc.creator.Lattes | http://lattes.cnpq.br/0624260902325890 | pt_BR |
dc.description.resumo | O bio-óleo do resíduo de sisal, produzido por meio do processo de pirólise rápida em leito fluidizado, possui uma composição diferenciada, que se destaca pela alta viscosidade e ponto de fluidez, baixa razão O/C, elevada estabilidade térmica e alto teor de fenóis. Porém, ele ainda precisa ter suas características melhoradas, a fim de ser utilizado em biorrefinarias e para a produção de espécies químicas de interesse industrial. Sendo assim, o presente trabalho tem o objetivo de avaliar a redução das espécies oxigenadas no bio-óleo do resíduo de sisal a partir da manipulação das variáveis operacionais do processo de pirólise rápida e da sua transformação catalítica via hidrodesoxigenação (HDO). As relações processo/produto da pirólise foram estudadas variando-se a vazão de nitrogênio, vazão mássica de biomassa, temperatura e pressão. Em geral, a composição do bio-óleo foi intensamente dependente dos parâmetros do processo. A menor pressão estudada foi a melhor condição para obtenção do bio-óleo com alto rendimento (até 17%), com maior rendimento de monômeros (44,51% em peso) e menor razão O/C (0,11). Os resultados também indicaram que o bio-óleo do resíduo de sisal apresenta uma composição com altos teores de compostos fenólicos, alifáticos e naftalenos. Ele possui, portanto, grande potencial para a obtenção de biocombustíveis e/ou aromáticos e fenóis de alto valor agregado via valorização catalítica, devido ao baixo teor de oxigênio e alto grau de despolimerização. Na etapa de HDO, os catalisadores do tipo Ni-Cu/Al-MCM-41 se mostraram ativos no hidrotratamento dos bio-óleos do resíduo do sisal e da madeira de pinho. Para o bio-óleo de pinho, os catalisadores bimetálicos 20Ni5Cu e 20Ni10Cu apresentaram as melhores performances, promovendo os rendimentos de 53,1% e 51,2% em fase oleosa, superiores ao do “benchmark” RU/C (47,1%), além de promoverem os rendimentos de 43,35% e 42,84% em peso de monômeros, respectivamente. Foi verificada a redução do peso molecular médio (Mw), assim como da razão O/C e aumento da razão H/C, indicando predominância da via reacional de hidrogenação/hidrodesoxigenação/hidrocraqueamento. No caso do bio-óleo do resíduo do sisal, a via de reação de repolimerização foi predominante, resultando em consumos de H2 mais baixos, aumento do Mw e redução dos rendimentos dos monômeros. Entretanto, foi verificada a redução da razão O/C de aproximadamente 48% em média em relação à entrada, assim como o aumento de hidrocarbonetos alifáticos, aromáticos, álcoois e cetonas. | pt_BR |
dc.publisher.department | Escola Politécnica | pt_BR |
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Journal of the Taiwan Institute of Chemical Engineers, v. 52, p. 147–157, 2015. | pt_BR |
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