https://repositorio.ufba.br/handle/ri/13811| metadata.dc.type: | Artigo de Periódico |
| Title: | Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite |
| Other Titles: | Reaction Kinetics and Catalysis Letters |
| Authors: | Vieira, Rinaldo Antonio de Melo Pires, Carlos A. M. Suñé, Leticia S. V. S. Silva, Antonio O. S. Souza, Marcelo José Barros de Araujo, Antonio S. |
| metadata.dc.creator: | Vieira, Rinaldo Antonio de Melo Pires, Carlos A. M. Suñé, Leticia S. V. S. Silva, Antonio O. S. Souza, Marcelo José Barros de Araujo, Antonio S. |
| Abstract: | The catalytic oxidation of phenol over CuZSM-12 (SAR = 200) has been studied using a semi-batch slurry reactor at temperatures of 110, 120 and 130oC, and acidic neutral and basic pH. At 130oC, the phenol undergoes total conversion to carbon dioxide and water in 1.5 h. The kinetic parameters were evaluated using a modified homogeneous heterogeneous model for the experimental data. Using this modified model, the activation energy for the catalytic oxidation process was ca. 90 kJ mol-1. |
| Keywords: | Phenol oxidation CuZSM-12 zeolite Slurry reactor Kinetic model |
| metadata.dc.rights: | Acesso Aberto |
| URI: | http://repositorio.ufba.br/ri/handle/ri/13811 |
| Issue Date: | 2006 |
| Appears in Collections: | Artigo Publicado em Periódico (PPEQ) |
| File | Description | Size | Format | |
|---|---|---|---|---|
| 10.1007_s11144-006-0118-z.pdf | 95,04 kB | Adobe PDF | View/Open |
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