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|Title: ||2-(2-Thiazolylazo)-p-cresol (TAC) as a reagent for the spectrophotometric determination of indium(III)|
|Other Titles: ||Microchemical Journal|
|Authors: ||Ferreira, Sergio Luis Costa|
Costa, Antonio Celso Spinola
Andrade, H. A. S.
|Issue Date: ||1991|
|Publisher: ||Microchemical Journal|
|Abstract: ||The reaction between indium(III) and the 2-(2-thiazolylazo)-p-cresol (TAC) in aqueous methanol media at apparent pH 5.0–6.0 results in an intensely colored complex which is stable for at least 2 h. The composition is 1:2 cation: TAC and the log of the formation constant is 10.78 ± 0.64. Beer's law is obeyed up to 8.0 μg · ml−1 of indium(III) at 580 nm. The apparent molar absorptivity at 580 nm is 1.21 × 104 liter · mol−1 · cm−1 and the detection limit was obtained as 10.0 ng · ml−1 of indium(III). The method is applied to the determination of indium in a catalyst.|
|Description: ||Texto completo: acesso restrito. p. 63-66|
|Appears in Collections:||Artigos Publicados em Periódicos (Quimica)|
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