1. Universidade Federal da Bahia
  2. Escola Politécnica
  3. Programa de Pós-Graduação em Engenharia Química (PPEQ)
  4. Tese (PPEQ)
Use este identificador para citar ou linkar para este item: https://repositorio.ufba.br/handle/ri/38522
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Campo DCValorIdioma
dc.creatorPereira, Luis Gabriel Gomes-
dc.date.accessioned2023-11-21T15:55:27Z-
dc.date.available2023-11-21T15:55:27Z-
dc.date.issued2023-09-15-
dc.identifier.urihttps://repositorio.ufba.br/handle/ri/38522-
dc.description.abstractBio-oil from sisal residue, produced through the process of fast pyrolysis in a fluidized bed, has a differentiated composition, which stands out due to its high viscosity and pour point, low O/C ratio, high thermal stability and high content of phenols. However, it still needs to be improved in order to be used in biorefineries and for the production of chemical species of industrial interest. Therefore, the present work aims to evaluate the reduction of oxygenated species in the bio-oil from sisal residue by manipulating the operational variables of the fast pyrolysis process and its catalytic transformation via hydrodeoxygenation (HDO). The process/product relations of the pyrolysis were studied by varying the nitrogen flow rate, biomass mass flow rate, temperature and pressure. In general, the bio-oil composition was intensely dependent on the process parameters. The lowest pressure studied was the best condition for obtaining bio-oil with high yield (up to 17 wt%), with higher yield of monomers (44.51 wt%) and lower O/C ratio (0.11). The results also indicated that the bio-oil from the sisal residue has a composition with high levels of phenolic, aliphatic and naphthalene compounds. It has, therefore, great potential for obtaining biofuels and/or aromatics and phenols with high added value via catalytic upgrade, due to the low oxygen content and high degree of depolymerization. In the HDO step, Ni-Cu/Al-MCM-41 type catalysts were active in the hydrotreatment of bio-oils from sisal residue and pinewood. The bimetallic catalysts 20Ni5Cu and 20Ni10Cu showed the best performances, promoting yields of 53.1 wt% and 51.2 wt% in the organic phase, higher than the benchmark RU/C (47.1%), in addition to promoting yields of 43.35 wt% and 42.84 wt% of monomers, respectively. There was a reduction in the average molecular weight (Mw), as well as in the O/C ratio and an increase in the H/C ratio, indicating a predominance of the hydrogenation/hydrodeoxygenation/hydrocracking route. In the case of bio-oil from sisal residue, the repolymerization route was predominant, resulting in lower H2 uptake, increased Mw and reduced monomer yields. However, there was a reduction in the O/C ratio of approximately 48 wt% on average compared to the feed, as well as an increase in aliphatic and aromatic hydrocarbons, alcohols and ketones.pt_BR
dc.description.sponsorshipCapespt_BR
dc.description.sponsorshipFAPESBpt_BR
dc.description.sponsorshipBanco do Nordestept_BR
dc.languageporpt_BR
dc.publisherUniversidade Federal da Bahiapt_BR
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Brazil*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/br/*
dc.subjectBio-óleopt_BR
dc.subjectResíduo de sisalpt_BR
dc.subjectPirólise rápidapt_BR
dc.subjectHidrodesoxigenação catalíticapt_BR
dc.subjectNi-Cu/Al-MCM-41pt_BR
dc.subject.otherBio-oilpt_BR
dc.subject.otherSisal residuept_BR
dc.subject.otherFast pyrolysispt_BR
dc.subject.otherCatalytic hydrotreatmentpt_BR
dc.subject.otherNi-Cu/Al-MCM-41pt_BR
dc.titleValorização do bio-óleo do resíduo de sisalpt_BR
dc.title.alternativeValorization of bio-oil from sisal residuept_BR
dc.typeTesept_BR
dc.contributor.refereesCampos, Leila Maria Aguilera-
dc.publisher.programPrograma de Pós-Graduação em Engenharia Quimica (PPEQ) pt_BR
dc.publisher.initialsUFBApt_BR
dc.publisher.countryBrasilpt_BR
dc.subject.cnpqCNPQ::ENGENHARIAS::ENGENHARIA QUIMICA::PROCESSOS INDUSTRIAIS DE ENGENHARIA QUIMICA::PROCESSOS ORGANICOSpt_BR
dc.contributor.advisor1Pires, Carlos Augusto de Moraes-
dc.contributor.advisor1IDhttps://orcid.org/0000-0003-4231-6495pt_BR
dc.contributor.advisor1Latteshttp://lattes.cnpq.br/7185462874845405pt_BR
dc.contributor.advisor-co1Lima, Sirlene Barbosa-
dc.contributor.advisor-co1Latteshttp://lattes.cnpq.br/4677727390063135pt_BR
dc.contributor.referee1Pires, Carlos Augusto de Moraes-
dc.contributor.referee1IDhttps://orcid.org/0000-0003-4231-6495pt_BR
dc.contributor.referee1Latteshttp://lattes.cnpq.br/7185462874845405pt_BR
dc.contributor.referee2Lima, Sirlene Barbosa-
dc.contributor.referee2Latteshttp://lattes.cnpq.br/4677727390063135pt_BR
dc.contributor.referee3Trierweiler, Jorge Otávio-
dc.contributor.referee3IDhttps://orcid.org/0000-0002-6328-945Xpt_BR
dc.contributor.referee3Latteshttp://lattes.cnpq.br/5718970374865864pt_BR
dc.contributor.referee4Silva Júnior, Roberto Batista da-
dc.contributor.referee4IDhttps://orcid.org/0000-0002-6281-7820pt_BR
dc.contributor.referee4Latteshttp://lattes.cnpq.br/8404741392766812pt_BR
dc.contributor.referee5Varela, Maria do Carmo Rangel Santos-
dc.contributor.referee5IDhttps://orcid.org/0000-0002-2497-9837pt_BR
dc.contributor.referee5Latteshttp://lattes.cnpq.br/0023950321397451pt_BR
dc.creator.IDhttps://orcid.org/0000-0002-1055-0300pt_BR
dc.creator.Latteshttp://lattes.cnpq.br/0624260902325890pt_BR
dc.description.resumoO bio-óleo do resíduo de sisal, produzido por meio do processo de pirólise rápida em leito fluidizado, possui uma composição diferenciada, que se destaca pela alta viscosidade e ponto de fluidez, baixa razão O/C, elevada estabilidade térmica e alto teor de fenóis. Porém, ele ainda precisa ter suas características melhoradas, a fim de ser utilizado em biorrefinarias e para a produção de espécies químicas de interesse industrial. Sendo assim, o presente trabalho tem o objetivo de avaliar a redução das espécies oxigenadas no bio-óleo do resíduo de sisal a partir da manipulação das variáveis operacionais do processo de pirólise rápida e da sua transformação catalítica via hidrodesoxigenação (HDO). As relações processo/produto da pirólise foram estudadas variando-se a vazão de nitrogênio, vazão mássica de biomassa, temperatura e pressão. Em geral, a composição do bio-óleo foi intensamente dependente dos parâmetros do processo. A menor pressão estudada foi a melhor condição para obtenção do bio-óleo com alto rendimento (até 17%), com maior rendimento de monômeros (44,51% em peso) e menor razão O/C (0,11). Os resultados também indicaram que o bio-óleo do resíduo de sisal apresenta uma composição com altos teores de compostos fenólicos, alifáticos e naftalenos. Ele possui, portanto, grande potencial para a obtenção de biocombustíveis e/ou aromáticos e fenóis de alto valor agregado via valorização catalítica, devido ao baixo teor de oxigênio e alto grau de despolimerização. Na etapa de HDO, os catalisadores do tipo Ni-Cu/Al-MCM-41 se mostraram ativos no hidrotratamento dos bio-óleos do resíduo do sisal e da madeira de pinho. Para o bio-óleo de pinho, os catalisadores bimetálicos 20Ni5Cu e 20Ni10Cu apresentaram as melhores performances, promovendo os rendimentos de 53,1% e 51,2% em fase oleosa, superiores ao do “benchmark” RU/C (47,1%), além de promoverem os rendimentos de 43,35% e 42,84% em peso de monômeros, respectivamente. Foi verificada a redução do peso molecular médio (Mw), assim como da razão O/C e aumento da razão H/C, indicando predominância da via reacional de hidrogenação/hidrodesoxigenação/hidrocraqueamento. No caso do bio-óleo do resíduo do sisal, a via de reação de repolimerização foi predominante, resultando em consumos de H2 mais baixos, aumento do Mw e redução dos rendimentos dos monômeros. Entretanto, foi verificada a redução da razão O/C de aproximadamente 48% em média em relação à entrada, assim como o aumento de hidrocarbonetos alifáticos, aromáticos, álcoois e cetonas.pt_BR
dc.publisher.departmentEscola Politécnicapt_BR
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